State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China.
Chem Commun (Camb). 2018 Dec 20;55(2):210-213. doi: 10.1039/c8cc09084j.
Iridium(iii)-induced selective B(2,3)-H and C-H bond activations at mono- and bi-p-methoxybenzeneazo-substituted m-carboranes have been investigated. A powerful methodology is introduced for the preparation of unique polynuclear complexes featuring m-carboranyl ligands in a single step. The experimental results highlight that the base employed in the reaction plays a key role in the formation and the structures of the complexes.
研究了铱(III)诱导的单取代和双取代对甲氧基苯偶氮基间二硼烷的 B(2,3)-H 和 C-H 键的选择性活化。本文介绍了一种在一步反应中制备具有独特多核配合物的新方法，该多核配合物的特征为单硼烷配体。实验结果表明，反应中所使用的碱在配合物的形成和结构中起着关键作用。
