Sotiles Anne Raquel, Baika Loana Mara, Grassi Marco Tadeu, Wypych Fernando
Departamento de Química , Universidade Federal do Paraná , Caixa Postal 19032, Curitiba-PR , CEP - 81531-980 , Brazil.
J Am Chem Soc. 2019 Jan 9;141(1):531-540. doi: 10.1021/jacs.8b11389. Epub 2018 Dec 17.
Layered double hydroxides (LDHs) with similar compositions to the minerals shigaite, natroglaucocerinite, and motukoreaite were synthesized by co-precipitation with increasing pH and characterized by several instrumental techniques. These minerals have previously been described to occur only with sodium and sulfate (Na(HO))[MAl(OH)(SO)]·6HO (M = Mn, Mg, and Zn). These phases were synthesized successfully along with others containing lithium and potassium. Cation exchange reactions were performed in the presence of alkaline metal sulfates, and for the first time several instrumental techniques were employed to show that the cations can be totally exchanged without removing the intercalated sulfate anions. This class of compounds, traditionally considered to be anion exchangers, can also be considered cation exchangers, which opens new avenues for future scientific and industrial applications.
