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Converting Mn/Al layered double hydroxide anion exchangers into cation exchangers by topotactic reactions using alkali metal sulfate solutions.

作者信息

Sotiles Anne Raquel, Wypych Fernando

机构信息

Departamento de Química - Universidade Federal do Paraná, Caixa Postal 19032, Curitiba-PR, CEP-81531-980, Brazil.

出版信息

Chem Commun (Camb). 2019 Jul 2;55(54):7824-7827. doi: 10.1039/c9cc03491a.

DOI:10.1039/c9cc03491a
PMID:31215552
Abstract

Layered double hydroxides (LDHs), traditional anion exchangers, can be converted into cation exchangers by topotactic reactions using aqueous solutions of alkali metal sulfates. LDHs with the composition Mn2Al(OH)61/n·yH2O (An- = Cl- or NO3-, CO32-) were reacted with aqueous solutions of Na2SO4. The anion carbonate could only be partially replaced by sulfate.

摘要

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