Department of Civil Engineering, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Republic of Korea.
Department of Civil Engineering, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Republic of Korea.
J Photochem Photobiol B. 2019 Feb;191:18-25. doi: 10.1016/j.jphotobiol.2018.12.007. Epub 2018 Dec 12.
Bacterial and dye pollution are major problems with wastewater treatment. An increasing number of photocatalysts are being used in industry to kill bacterial and reduce pollution. In the present study, highly stable SnO-doped nanocomposites have been prepared successively by a hydrothermal method. The synthesized nanocomposite was characterized using a range of techniques, such as X-ray diffraction, field emission scanning electron microscopy with energy dispersive X-ray spectroscopy and electron probe micro analysis, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, and high resolution transmission electron microscopy (HR-TEM). The nanocomposites showed significant dose-dependent bactericidal activity in the disc diffusion assay and cell viability test. The S-GO-SnO 200 μg/mL produced a cell viability of 184.3 ± 11.71 and 172.3 ± 3.05 × 10 CFU/mL for E. coli and P. graminis, respectively. The S-GO-SnO showed significant photocatalytic degradation against MB in 120 min. The photocatalyst S-GO-SnO showed 159 and 161 × 10 CFU/mL at 150 min in E. coli and P. graminis, respectively. The cells treated with photocatalytic SnO-doped nanocomposites showed 50% cell death. HR-TEM revealed 50% cell growth inhibition by bacterial damage. This photocatalytic SnO-doped nanocomposite is a good candidate for treating industrial wastewater treatment contaminated with dyes and bacteria.
细菌和染料污染是废水处理的主要问题。越来越多的光催化剂被用于工业中以杀死细菌并减少污染。在本研究中,通过水热法成功制备了高度稳定的 SnO 掺杂纳米复合材料。使用一系列技术对合成的纳米复合材料进行了表征,例如 X 射线衍射、场发射扫描电子显微镜结合能谱和电子探针微分析、紫外-可见光谱、傅里叶变换红外光谱和高分辨率透射电子显微镜 (HR-TEM)。在圆盘扩散试验和细胞活力试验中,纳米复合材料表现出显著的剂量依赖性杀菌活性。S-GO-SnO 200μg/mL 对大肠杆菌和禾谷多黏菌的细胞活力分别为 184.3±11.71 和 172.3±3.05×10 CFU/mL。S-GO-SnO 对 MB 表现出显著的光催化降解作用,在 120 分钟内即可完成。在 150 分钟时,光催化剂 S-GO-SnO 对大肠杆菌和禾谷多黏菌的杀灭率分别达到 159 和 161×10 CFU/mL。经光催化 SnO 掺杂纳米复合材料处理的细胞显示出 50%的细胞死亡。高分辨率透射电子显微镜显示,细菌损伤导致 50%的细胞生长受到抑制。这种光催化 SnO 掺杂纳米复合材料是处理工业废水中染料和细菌污染的理想候选材料。