Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040-Madrid, Spain.
Chem Commun (Camb). 2019 Jan 16;55(5):675-678. doi: 10.1039/c8cc09777a. Epub 2018 Dec 19.
Geminal frustrated Lewis pairs (FLPs) having a borole fragment as the Lewis acid partner constitute really promising candidates to achieve facile small molecule activation reactions. The predicted enhanced reactivity of these species, as compared to more traditional FLPs, finds its origin in the loss of the antiaromatic character of the borole moiety along the reaction coordinate.
双齿受阻路易斯对（FLP），其路易斯酸配体为硼杂环戊二烯片段，是实现易小分子活化反应的极具前景的候选物。与传统的 FLP 相比，这些物种的预测增强的反应性源于硼杂环戊二烯部分在反应坐标上失去反芳香性特征。
