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Electric-Field Mediated Chemistry: Uncovering and Exploiting the Potential of (Oriented) Electric Fields to Exert Chemical Catalysis and Reaction Control.
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Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes.
J Am Chem Soc. 2020 Jun 24;142(25):10942-10954. doi: 10.1021/jacs.9b13769. Epub 2020 Jun 11.
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Negative Charge as a Lens for Concentrating Antiaromaticity: Using a Pentagonal "Defect" and Helicene Strain for Cyclizations.
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Excited-state proton transfer relieves antiaromaticity in molecules.
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Inverse-Electron-Demand oxa-Diels-Alder Reactions of α-Keto-β,γ-unsaturated Esters and α,β-Unsaturated Hydrazones.
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