铑(III)与钴(III)：使用 Cp*Rh 催化剂的具有不同机理的三组分 C-H 键加成级联反应。
Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C-H bond addition cascade using a Cp*Rh catalyst.
机构信息
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
出版信息
Chem Commun (Camb). 2019 Jan 10;55(5):695-698. doi: 10.1039/c8cc08792j.
PMID:30565600
Abstract
Three-component C-H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed C-H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman's CoIII-catalytic system to homoallylic alcohols.
摘要
三种不同偶联物的三组分 C-H 键加成反应仍未得到充分发展。在此，我们报道了首例三组分 RhIII 催化的 C-H 键加成反应，该反应适用于广泛的二烯和醛。我们的方法与 Ellman 的 CoIII 催化体系互补，为高烯丙醇提供了另一种途径。
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