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聚乳酸机械性能改善和降解加速的平行进展。

Parallel advances in improving mechanical properties and accelerating degradation to polylactic acid.

机构信息

College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China.

College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China.

出版信息

Int J Biol Macromol. 2019 Mar 15;125:1093-1102. doi: 10.1016/j.ijbiomac.2018.12.148. Epub 2018 Dec 18.

Abstract

Going up further on the basis of excellent mechanical properties and solving the long-standing shortcoming of the slow degradation rate were developed in parallel for polylactic acid (PLA). The polylactic acid/wood flour/polymethylmethacrylate (PLA/WF/PMMA) composites were prepared by melt blending used PLA as matrix, WF of diverse particle size with PMMA at 8:2 mass ratio totally filled with 20 wt%. The PLA/WF/PMMA composites were studied by means of Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), melting index test, and universal mechanical properties test. The result shows that WF of 150 μm < particle size < 180 μm executed the optimal improvement to mechanical properties of PLA/WF/PMMA. Tensile strength, flexural modulus and Young's modulus of PLA/WF/PMMA (150-180 μm) were enhanced 10.02%, 37.21% and 32.80% in relation to neat PLA, respectively. Hydrophilic contact angle test, water absorption measurement and hydrolysis assessment were performed to the hydrolysis degradation performance of materials. Furthermore, PMMA and WF cooperatively assisted in enormously accelerating hydrolysis of PLA, eventually having a good performance. Improving mechanical properties and accelerating degradation at the same time are of great significance for expanding the application of PLA.

摘要

进一步提高聚乳酸(PLA)的机械性能,并解决其降解速度缓慢的长期缺点,并行开发。通过熔融共混制备了聚乳酸/木粉/聚甲基丙烯酸甲酯(PLA/WF/PMMA)复合材料,以 PLA 为基体,以不同粒径的 WF 与 PMMA 按 8:2 的质量比共填充 20wt%。采用傅里叶变换红外光谱(FTIR)、差示扫描量热仪(DSC)、熔体流动指数测试和通用力学性能测试对 PLA/WF/PMMA 复合材料进行了研究。结果表明,粒径为 150μm<particle size<180μm 的 WF 对 PLA/WF/PMMA 的力学性能有最佳的改善作用。与纯 PLA 相比,PLA/WF/PMMA(150-180μm)的拉伸强度、弯曲模量和杨氏模量分别提高了 10.02%、37.21%和 32.80%。对材料的水解降解性能进行了亲水接触角测试、吸水率测量和水解评估。此外,PMMA 和 WF 协同作用极大地加速了 PLA 的水解,最终表现出良好的性能。同时提高力学性能和加速降解对扩大 PLA 的应用具有重要意义。

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