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草酸氢吡啶盐和草酸氢吗啉盐中的氢键链和二聚体基序。

Hydrogen-bonding chain and dimer motifs in pyridinium and morpholinium hydrogen oxalate salts.

作者信息

Mulrooney David Z T, Madden Eimear C, Lonergan Rhona F, Slyusarchuk Valentyna D, Müller-Bunz Helge, Keene Tony D

机构信息

School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.

出版信息

Acta Crystallogr E Crystallogr Commun. 2018 Nov 16;74(Pt 12):1804-1807. doi: 10.1107/S2056989018015827. eCollection 2018 Dec 1.

DOI:10.1107/S2056989018015827
PMID:30574378
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6281086/
Abstract

We present here three compounds consisting of pyridinium or morpholinium hydrogen oxalates, each displaying different hydrogen-bonding motifs, resulting in chains for 4-(di-methyl-amino)-pyridinium hydrogen oxalate 0.22-hydrate, CHN ·CHO ·0.22HO (), dimers for 4--butyl-pyridinium hydrogen oxalate, CHN·CHO (), and chains for morpholin-ium hydrogen oxalate, CHNO·CHO ().

摘要

我们在此展示了三种由吡啶鎓或吗啉鎓草酸氢盐组成的化合物，每种化合物都呈现出不同的氢键模式，导致草酸氢4-（二甲基氨基）吡啶鎓0.22水合物[C₇H₁₀N₂·C₂H₂O₄·0.22H₂O]形成链状结构，草酸氢4-正丁基吡啶鎓[C₉H₁₃N·C₂H₂O₄]形成二聚体，草酸吗啉鎓[C₄H₉NO·C₂H₂O₄]形成链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/5e8c2ce61c84/e-74-01804-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/36e223dbaa00/e-74-01804-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/46be7e7a2bec/e-74-01804-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/70c10d21afa8/e-74-01804-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/5e8c2ce61c84/e-74-01804-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/36e223dbaa00/e-74-01804-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/46be7e7a2bec/e-74-01804-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/70c10d21afa8/e-74-01804-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ed5/6281086/5e8c2ce61c84/e-74-01804-fig4.jpg

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