Zhang Dayu School of Chemistry , Dalian University of Technology , Dalian , Liaoning 116024 , China.
School of Science , Xi'an Jiaotong University , Xi'an , Shaanxi 710049 , China.
ACS Sens. 2019 Jan 25;4(1):152-160. doi: 10.1021/acssensors.8b01111. Epub 2019 Jan 9.
Detection of methanol is a significant segment for body health and work safety in the production of chemical industry. However, there hardly exists highly selective methanol detection system with green environment for vapor or liquid adaptability, as well as large linear relationship. A facile wearable vapor/liquid amphibious electrochemical sensor for monitoring methanol has been carried out for the first time in this Article. This wearable methanol sensor was fabricated by using a simple screen-printing technology for accomplishing a microdevice platform, showing good linear relationship, high selectivity (multiple volatile chemical compounds), reliable repeatability, good stability, and excellent stretching and bending performance (nitrile glove-based sensor) without pretreatment or adding any polymers into inks. Owing to its good environmental adaptability of vapor or liquid and various sensing behaviors (high sensitivity and wide linear range) by being modified with different content of platinum catalyst, this methanol sensor would have tremendous potential application for environmental monitoring on smart wearable devices when employed based on various platforms (such as PET, cotton, and nitrile gloves).
甲醇的检测在化工生产中的人体健康和工作安全方面是一个重要的环节。然而,目前几乎没有具有绿色环境适应性、蒸气或液体适应性以及大线性关系的高选择性甲醇检测系统。本文首次提出了一种简便的可穿戴蒸气/液体两栖电化学传感器,用于监测甲醇。该可穿戴甲醇传感器是通过使用简单的丝网印刷技术来制造微器件平台来实现的,具有良好的线性关系、高选择性(多种挥发性化合物)、可靠的重复性、良好的稳定性和出色的拉伸和弯曲性能(基于丁腈手套的传感器),无需预处理或在油墨中添加任何聚合物。由于其蒸气或液体的良好环境适应性以及通过修饰不同含量的铂催化剂而表现出的各种传感行为(高灵敏度和宽线性范围),这种甲醇传感器在基于各种平台(如 PET、棉花和丁腈手套)的智能可穿戴设备上进行环境监测时,将具有巨大的潜在应用价值。