Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions.

Mixed cyclotrimerization reactions of diarylacetylenes (tolans) were applied to generate a library of multiple porphyrin-hexaphenylbenzene (HPB) architectures. Successful reactions, which could be influenced by the ratio of tolan starting materials, were conducted using dicobaltoctacarbonyl as a catalyst. Separation of the reaction products was performed by chromatographic and crystallization techniques. The physical properties were investigated with respect to the number of porphyrins per HPB and their substitution pattern.