Three-in-One Oxygen Vacancies: Whole Visible-Spectrum Absorption, Efficient Charge Separation, and Surface Site Activation for Robust CO Photoreduction.

A facile and controllable in situ reduction strategy is used to create surface oxygen vacancies (OVs) on Aurivillius-phase Sr Bi Nb TiO nanosheets, which were prepared by a mineralizer-assisted soft-chemical method. Introduction of OVs on the surface of Sr Bi Nb TiO extends photoresponse to cover the whole visible region and also tremendously promotes separation of photoinduced charge carriers. Adsorption and activation of CO molecules on the surface of the catalyst are greatly enhanced. In the gas-solid reaction system without co-catalysts or sacrificial agents, OVs-abundant Sr Bi Nb TiO nanosheets show outstanding CO photoreduction activity, producing CO with a rate of 17.11 μmol g  h , about 58 times higher than that of the bulk counterpart, surpassing most previously reported state-of-the-art photocatalysts. Our study provides a three-in-one integrated solution to advance the performance of photocatalysts for solar-energy conversion and generation of renewable energy.