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快速、灵敏、选择性和可逆的气相中 TATP 的荧光监测。

Fast, sensitive, selective and reversible fluorescence monitoring of TATP in a vapor phase.

机构信息

Key Laboratory of Applied Surface and Colloid Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China.

出版信息

Chem Commun (Camb). 2019 Jan 17;55(7):941-944. doi: 10.1039/c8cc08399a.

Abstract

The development of sensors for the detection of triacetone triperoxide (TATP) has attracted great attention. Here, we constructed a low-cost, portable, reusable, visible paper-based fluorescent sensor for the sensitive detection of TATP via vapor sampling. Under optimized conditions, the fluorescent film showed a high sensitivity to TATP with a detection limit of lower than 0.5 μg mL-1 in air. The linear range of the response is from 0.5 to 8.0 μg mL-1. In addition, the paper-based sensor exhibited high selectivity to TATP. The presence of potential interferents showed little effect on sensing. Moreover, sensing is fully reversible. Fortunately, the test can also be conducted in a visualized way.

摘要

用于检测三过氧化三丙酮(TATP)的传感器的发展引起了极大的关注。在这里,我们构建了一种低成本、便携式、可重复使用的可见型纸质荧光传感器,通过蒸气采样实现对 TATP 的灵敏检测。在优化条件下,荧光膜对 TATP 具有很高的灵敏度,空气中的检测限低于 0.5μg mL-1。响应的线性范围为 0.5 至 8.0μg mL-1。此外,基于纸张的传感器对 TATP 表现出很高的选择性。潜在干扰物的存在对感测几乎没有影响。此外,感测是完全可逆的。幸运的是,测试也可以以可视化的方式进行。

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