卟啉钴过氧化物配合物的氢原子转移反应性。
The hydrogen atom transfer reactivity of a porphyrinoid cobalt superoxide complex.
机构信息
Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA.
出版信息
Chem Commun (Camb). 2019 Jan 17;55(7):913-916. doi: 10.1039/c8cc08453j.
Abstract
The H-atom transfer (HAT) reactivity of a corrolazine cobalt superoxide with weak O-H and N-H substrates has been demonstrated. Kinetic analysis shows relatively fast rates of HAT with diphenylhydrazine (DPH). A kinetic isotope effect (KIE) and Eyring activation parameters are consistent with an HAT mechanism.
摘要
已经证明了具有弱 O-H 和 N-H 底物的冠状钴超氧化物的 H-原子转移 (HAT) 反应性。动力学分析表明与二苯肼 (DPH) 的 HAT 具有相对较快的速率。动力学同位素效应 (KIE) 和 Eyring 活化参数与 HAT 机制一致。
相似文献
1
The hydrogen atom transfer reactivity of a porphyrinoid cobalt superoxide complex.卟啉钴过氧化物配合物的氢原子转移反应性。
Chem Commun (Camb). 2019 Jan 17;55(7):913-916. doi: 10.1039/c8cc08453j.
2
meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert Re(O) corrolazine.卟啉类配合物的中-N-甲基化：激活惰性Re(O) 咕啉嗪的氢原子转移能力
Chem Commun (Camb). 2017 Feb 7;53(12):1961-1964. doi: 10.1039/c6cc09341h.
3
A high-valent iron-oxo corrolazine activates C-H bonds via hydrogen-atom transfer.高价铁氧代corrolazine 通过氢原子转移激活 C-H 键。
J Am Chem Soc. 2012 May 2;134(17):7392-9. doi: 10.1021/ja3018658. Epub 2012 Apr 24.
4
Understanding Biological Hydrogen Transfer Through the Lens of Temperature Dependent Kinetic Isotope Effects.理解温度依赖的动力学同位素效应下的生物氢转移。
Acc Chem Res. 2018 Sep 18;51(9):1966-1974. doi: 10.1021/acs.accounts.8b00226. Epub 2018 Aug 28.
5
Switchover of the Mechanism between Electron Transfer and Hydrogen-Atom Transfer for a Protonated Manganese(IV)-Oxo Complex by Changing Only the Reaction Temperature.仅通过改变反应温度即可实现质子化锰(IV)-氧配合物中电子转移和氢原子转移机制的转换。
Angew Chem Int Ed Engl. 2016 Jun 20;55(26):7450-4. doi: 10.1002/anie.201602460. Epub 2016 May 18.
6
Manganese-Oxygen Intermediates in O-O Bond Activation and Hydrogen-Atom Transfer Reactions.锰-氧中间体在 O-O 键活化和氢原子转移反应中的作用。
Acc Chem Res. 2017 Nov 21;50(11):2706-2717. doi: 10.1021/acs.accounts.7b00343. Epub 2017 Oct 24.
7
The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.外围取代基修饰对P(V)、Mn(III)和Mn(V)(O) 咕啉的影响：X射线晶体学、电化学和光谱性质以及氢原子转移（HAT）和氧原子转移（OAT）反应活性
Inorg Chem. 2016 Sep 6;55(17):8646-60. doi: 10.1021/acs.inorgchem.6b01219. Epub 2016 Aug 16.
8
A Continuum of Proton-Coupled Electron Transfer Reactivity.质子耦合电子转移反应性的连续统。
Acc Chem Res. 2018 Oct 16;51(10):2391-2399. doi: 10.1021/acs.accounts.8b00319. Epub 2018 Sep 20.
9
A Balancing Act: Stability versus Reactivity of Mn(O) Complexes.一种平衡行为：锰（氧）配合物的稳定性与反应活性
Acc Chem Res. 2015 Oct 20;48(10):2754-64. doi: 10.1021/acs.accounts.5b00273. Epub 2015 Sep 9.
10
Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid Complexes.与锰（V）（氧）卟啉类配合物相比，锰（IV）（氧）（π - 自由基阳离子）（路易斯酸）的氧原子转移反应活性受到强烈抑制。
J Am Chem Soc. 2015 May 27;137(20):6531-40. doi: 10.1021/jacs.5b00875. Epub 2015 May 12.
引用本文的文献
1
Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an Unusual = 3/2 Ground State that Promotes N-Group and Hydrogen Atom-Transfer Reactions with Exogenous Substrates.具有不寻常的S = 3/2基态的六配位钴（III）-亚胺基配合物的生成、光谱表征及计算分析，该配合物可促进与外源底物的N-基团和氢原子转移反应。
J Am Chem Soc. 2023 Dec 6;145(48):26106-26121. doi: 10.1021/jacs.3c08117. Epub 2023 Nov 24.
2
An Iron(III) Superoxide Corrole from Iron(II) and Dioxygen.铁（III）过氧卟啉配合物由铁（II）和氧气生成。
Angew Chem Int Ed Engl. 2022 Jan 10;61(2):e202111492. doi: 10.1002/anie.202111492. Epub 2021 Nov 30.
3
Proton-coupled electron transfer reactivities of electronically divergent heme superoxide intermediates: a kinetic, thermodynamic, and theoretical study.电子发散血红素超氧化物中间体的质子耦合电子转移反应活性：动力学、热力学及理论研究
Chem Sci. 2021 May 27;12(25):8872-8883. doi: 10.1039/d1sc01952j. eCollection 2021 Jul 1.
4
Mononuclear Manganese(III) Superoxo Complexes: Synthesis, Characterization, and Reactivity.单核锰（III）超氧配合物：合成、表征及反应活性
Inorg Chem. 2019 Aug 5;58(15):9756-9765. doi: 10.1021/acs.inorgchem.9b00767. Epub 2019 Jul 22.
本文引用的文献
1
Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from Co and O.捕获由钴（Co）和氧（O）可逆形成的超氧钴物种和过氧二钴物种。
Chem Commun (Camb). 2017 Aug 22;53(86):11782-11785. doi: 10.1039/c7cc05904c.
2
Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.氧衍生锰和铁卟啉类配合物的仿生反应活性
Chem Rev. 2017 Nov 8;117(21):13320-13352. doi: 10.1021/acs.chemrev.7b00180. Epub 2017 Oct 9.
3
Hydrogen Atom Abstraction Thermodynamics of a μ-1,2-Superoxo Dicopper(II) Complex.μ-1,2-过氧二合铜(II)配合物的氢原子攫取热力学
J Am Chem Soc. 2017 Jul 26;139(29):9831-9834. doi: 10.1021/jacs.7b05722. Epub 2017 Jul 13.
4
A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from Its Superoxo Intermediate via Hydrogen Atom Abstraction.通过氢原子攫取，从其过氧自由基中间产物得到结构确证的非血红素钴-过氧配合物。
J Am Chem Soc. 2016 Nov 2;138(43):14186-14189. doi: 10.1021/jacs.6b08642. Epub 2016 Oct 20.
5
Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.铁锰配合物对氧气的活化：血红素和非血红素的观点。
J Am Chem Soc. 2016 Sep 14;138(36):11410-28. doi: 10.1021/jacs.6b05251. Epub 2016 Aug 30.
6
An iron-oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase.在半胱氨酸双加氧酶催化循环过程中形成的铁 - 氧中间体。
Chem Commun (Camb). 2016 Jul 7;52(57):8814-7. doi: 10.1039/c6cc03904a.
7
Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase.曲霉属 nidulans 异青霉素 N 合酶的两种 C-H-C 裂解中间体的光谱证据。
J Am Chem Soc. 2016 Jul 20;138(28):8862-74. doi: 10.1021/jacs.6b04065. Epub 2016 Jul 5.
8
The secondary coordination sphere controlled reactivity of a ferric-superoxo heme: unexpected conversion to a ferric hydroperoxo intermediate by reaction with a high-spin ferrous heme.二级配位层控制的铁-超氧血红素的反应活性：与高自旋亚铁血红素反应意外转化为铁-氢过氧中间体。
Chem Commun (Camb). 2016 Jun 7;52(45):7213-6. doi: 10.1039/c6cc02162j. Epub 2016 Apr 22.
9
Substrate Oxidation by Indoleamine 2,3-Dioxygenase: EVIDENCE FOR A COMMON REACTION MECHANISM.吲哚胺2,3-双加氧酶催化的底物氧化：共同反应机制的证据
J Biol Chem. 2015 Dec 25;290(52):30924-30. doi: 10.1074/jbc.M115.695684. Epub 2015 Oct 28.
10
Tuning the Reactivity of Chromium(III)-Superoxo Species by Coordinating Axial Ligands.通过配位轴向配体调节铬（III）-超氧物种的反应活性
Inorg Chem. 2015 Nov 2;54(21):10513-20. doi: 10.1021/acs.inorgchem.5b02068. Epub 2015 Oct 21.
Zotero 插件