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[中国东南部汉江流域土壤样品中有机氯农药(OCPs)的特征]

[Characteristics of Organochlorine Pesticides (OCPs) in Soil Samples of Hanjiang River Basin, Southeast China].

作者信息

Liu Jia, Ding Yang, Qi Shi-Hua, Qu Cheng-Kai

机构信息

School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China.

State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, Wuhan 430074, China.

出版信息

Huan Jing Ke Xue. 2018 Nov 8;39(11):5127-5134. doi: 10.13227/j.hjkx.201802080.

Abstract

Seventeen soil samples were collected along the main stream of the Hanjiang River in April 2013. Thirteen types of organochlorine pesticides (OCPs) were detected in the samples by gas chromatography with a Ni electron capture detector. The purpose of this study was to investigate the distribution, composition, and source of OCPs and assess the potential health risks for local residents. The 13 types of OCPs were all detected in this region, ranging from 2.97 ng·g to 1275.79 ng·g, and the detection rates were 75%-100%. The contribution trends of both hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) were upstream < midstream < downstream. Based on the ratio method, the HCHs were mainly from technical HCH input. Furthermore, there was DDT input recently, which contained industrial DDT and dicofol. The DDTs concentrations significantly correlated with total organic carbon. The values of cancer and non-cancer risks (10-10 and 10-10) were both lower than the corresponding thresholds (10 and 1), which indicated that the soils in the Hanjiang River Basin had no harmful effects on local residents.

摘要

2013年4月,在汉江干流沿线采集了17份土壤样本。采用配有镍电子捕获检测器的气相色谱法检测样本中的13种有机氯农药(OCPs)。本研究的目的是调查OCPs的分布、组成和来源,并评估对当地居民的潜在健康风险。该地区检测出了所有13种OCPs,含量范围为2.97 ng·g至1275.79 ng·g,检出率为75%-100%。六氯环己烷(HCHs)和二氯二苯三氯乙烷(DDTs)的贡献趋势均为上游<中游<下游。基于比值法,HCHs主要来源于工业六六六的输入。此外,近期存在DDT输入,其中包括工业DDT和三氯杀螨醇。DDTs浓度与总有机碳显著相关。癌症风险和非癌症风险值(10-10和10-10)均低于相应阈值(10和1),这表明汉江流域土壤对当地居民无有害影响。

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