Université libre de Bruxelles (ULB), Nonlinear Physical Chemistry Unit, Faculté des Sciences, CP-231, 1050 Brussels, Belgium.
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA.
Soft Matter. 2019 Jan 28;15(4):803-812. doi: 10.1039/c8sm01928b. Epub 2019 Jan 15.
Filiform corrosion produces long and narrow trails on various coated metals through the detachment of the coating layer from the substrate. In this work, we present a combined experimental and theoretical analysis of this process with the aim to describe quantitatively the shape of the cross-section, perpendicular to the direction of propagation, of the filaments produced. For this purpose, we introduce a delamination model of filiform corrosion dynamics and show its compatibility with experimental data where the coating thickness has been varied systematically.
丝状腐蚀会导致各种涂覆金属表面出现狭长的痕迹,这是由于涂层从基底上脱落所致。在这项工作中,我们通过实验和理论分析相结合的方法研究了这一过程,旨在定量描述垂直于传播方向的丝状腐蚀产物的横截面形状。为此,我们引入了丝状腐蚀动力学的分层模型,并展示了该模型与实验数据的兼容性,其中系统地改变了涂层厚度。