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层状类电纺介孔Ti-Al-O纳米纤维

Lamellar-like Electrospun Mesoporous Ti-Al-O Nanofibers.

作者信息

Elishav Oren, Poliak Liz, Naamat Iris, Beilin Vadim, Shter Gennady E, Grader Gideon S

机构信息

The Nancy and Stephen Grand Technion Energy Program, Technion-Israel Institute of Technology, Haifa 3200003, Israel.

The Wolfson Department of Chemical Engineering, Technion ⁻ Israel Institute of Technology, Haifa 3200003, Israel.

出版信息

Materials (Basel). 2019 Jan 14;12(2):252. doi: 10.3390/ma12020252.

DOI:10.3390/ma12020252
PMID:30646558
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6356458/
Abstract

Ceramic oxides nanofibers are promising materials as catalysts, electrodes and functional materials. In this report, a unique lamellar-like mesoporous structure was realized for the first time in a new system based on titania and alumina. The final structure was found to be highly dependent on the process conditions which are outlined herein. In view of the similar architecture we recently obtained with Fe-Al-O fibers, the pore formation mechanism we outline herein is general and is applicable to additional systems.

摘要

陶瓷氧化物纳米纤维作为催化剂、电极和功能材料是很有前景的材料。在本报告中,首次在基于二氧化钛和氧化铝的新体系中实现了独特的层状介孔结构。发现最终结构高度依赖于本文所述的工艺条件。鉴于我们最近用铁铝氧化物纤维获得了类似的结构,我们在此概述的孔形成机制是通用的,适用于其他体系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/8009aa3648a4/materials-12-00252-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/1477105b6062/materials-12-00252-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/2f36640985c5/materials-12-00252-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/afcf1249bb23/materials-12-00252-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/337ec1816015/materials-12-00252-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/e85a6b2fc858/materials-12-00252-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/8009aa3648a4/materials-12-00252-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/1477105b6062/materials-12-00252-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/2f36640985c5/materials-12-00252-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/afcf1249bb23/materials-12-00252-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/337ec1816015/materials-12-00252-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/e85a6b2fc858/materials-12-00252-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8e5/6356458/8009aa3648a4/materials-12-00252-g006.jpg

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本文引用的文献

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High-Temperature Stable Anatase Titanium Oxide Nanofibers for Lithium-Ion Battery Anodes.用于锂离子电池负极的高温稳定锐钛矿型二氧化钛纳米纤维。
ACS Appl Mater Interfaces. 2017 Aug 2;9(30):25332-25338. doi: 10.1021/acsami.7b06631. Epub 2017 Jul 24.
2
Ordered mesoporous materials based on interfacial assembly and engineering.基于界面组装和工程的有序介孔材料。
Adv Mater. 2013 Oct 4;25(37):5129-52, 5128. doi: 10.1002/adma.201302184. Epub 2013 Jul 19.
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Nanosheet-constructed porous TiO2-B for advanced lithium ion batteries.纳米片构建的多孔 TiO2-B 用于先进的锂离子电池。
Adv Mater. 2012 Jun 26;24(24):3201-4. doi: 10.1002/adma.201201036. Epub 2012 May 18.
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Novel hollow mesoporous 1D TiO2 nanofibers as photovoltaic and photocatalytic materials.新型中空介孔 1D TiO2 纳米纤维作为光电和光催化材料。
Nanoscale. 2012 Mar 7;4(5):1707-16. doi: 10.1039/c2nr11251e. Epub 2012 Feb 8.
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Anatase mesoporous TiO2 nanofibers with high surface area for solid-state dye-sensitized solar cells.具有高比表面积的锐钛矿介孔 TiO2 纳米纤维用于固态染料敏化太阳能电池。
Small. 2010 Oct 4;6(19):2176-82. doi: 10.1002/smll.201000759.
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Electrospinning: a fascinating method for the preparation of ultrathin fibers.静电纺丝:一种制备超细纤维的迷人方法。
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Mesoporous titania spheres with tunable chamber stucture and enhanced photocatalytic activity.具有可调腔室结构和增强光催化活性的介孔二氧化钛球体。
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