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单独及复合添加钛和铈的再生Al-Si-Cu-Fe-Mn合金的微观结构与拉伸性能表征

Characterization of Microstructures and Tensile Properties of Recycled Al-Si-Cu-Fe-Mn Alloys with Individual and Combined Addition of Titanium and Cerium.

作者信息

Wang Kang, Tang Peng, Huang Yi, Zhao Yanjun, Li Wenfang, Tian Jun

机构信息

School of Mechanical Engineering, Dongguan University of Technology, Dongguan, 523000 Guangdong, China.

Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, Nanning, 530004 Guangxi, China.

出版信息

Scanning. 2018 Dec 17;2018:3472743. doi: 10.1155/2018/3472743. eCollection 2018.

Abstract

Individual and combined addition of Ti and Ce on the recycled Al-Si-Cu-Fe-Mn alloy was conducted. The microstructures and tensile properties of these fabricated alloys were investigated. In the case of Ti or Ce which was individually added, the added amount was ranging from 0.03 wt.% to 0.09 wt.%. The combined addition of Ti and Ce was set at the ratios of 1 : 1, 1 : 3, and 3 : 1 with a total amount of 0.12 wt.%. Microstructures and phases of these alloys were investigated by using an optical microscope, X-ray diffraction testing, and SEM coupled with EDS. The morphologies of these alloys were quantified by analyzing the SDAS value, length of secondary phases, and phases' distribution uniformity. Tensile testing was carried out for understanding the strengthen effect of the modification process. Results show that the addition of Ce was favorable to the strength and % elongation because the coarse needle-like phase and the polyhedral phase were effectively refined. Their SDAS values and distribution factor were remarkably declined with the increase of the Ce level. The Ti addition could also refine the secondary phases and SDAS values. But its effect was not as prominent as the addition of Ce. Combined addition of Ti and Ce elements at the ratio of 1 : 3 resulted in the samples reaching maximum comprehensive tensile properties. In this case, the short needle-like phase was uniformly distributed in the microstructure. Few polyhedral phases could be found in the Al-Si-Cu-Fe-Mn matrix. The strengthening of these fabricated materials was due to the grain refinement for -Al and modification for coarse secondary phases. In addition, distribution uniformity of secondary phases was also changed by their modification effects.

摘要

对再生Al-Si-Cu-Fe-Mn合金进行了Ti和Ce的单独添加及复合添加。研究了这些制备合金的微观结构和拉伸性能。在单独添加Ti或Ce的情况下,添加量范围为0.03 wt.%至0.09 wt.%。Ti和Ce的复合添加设定为1∶1、1∶3和3∶1的比例,总量为0.12 wt.%。通过光学显微镜、X射线衍射测试以及与能谱仪联用的扫描电子显微镜对这些合金的微观结构和相进行了研究。通过分析二次枝晶臂间距值、第二相长度和相的分布均匀性对这些合金的形态进行了量化。进行拉伸试验以了解变质处理的强化效果。结果表明,添加Ce有利于提高强度和伸长率,因为粗大的针状相和多面体相得到了有效细化。随着Ce含量的增加,它们的二次枝晶臂间距值和分布系数显著下降。添加Ti也可以细化第二相和二次枝晶臂间距值。但其效果不如添加Ce显著。Ti和Ce元素按1∶3的比例复合添加导致样品达到最大综合拉伸性能。在这种情况下,短针状相均匀分布在微观结构中。在Al-Si-Cu-Fe-Mn基体中几乎找不到多面体相。这些制备材料的强化归因于对α-Al的晶粒细化和对粗大第二相的变质处理。此外,第二相的分布均匀性也因其变质效果而发生了变化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f47c/6311731/8f6fcb0bd847/SCANNING2018-3472743.001.jpg

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