College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004, PR China.
Jinhua Municipal Center Hospital, Jinhua 321000, PR China.
Ecotoxicol Environ Saf. 2019 Apr 30;171:813-822. doi: 10.1016/j.ecoenv.2018.12.106. Epub 2019 Jan 17.
Investigating the occurrence of disinfection by-products (DBPs) and identify the related influencing factors in drinking water is essentially important to control DBPs risk. In this study, 64 tap water samples were collected from 8 counties (or county level cities) in Jinhua Region of Zhejiang Province, China. Results showed that the median (range) of trihalomethane (THMs), haloacetic acids (HAAs), haloacetonitriles (HANs), haloketones (HKs) and halonitromethanes (HNMs) were 23.2 (9.1-40.9), 15.3 (5.8-38.6), 2.2 (0.7-7.6), 2.1 (0.2-6.4) and 0.7 (0.2-2.9) µg/L, respectively. HAAs, HANs, HKs and HNMs levels were generally higher in summer than in winter or spring, while for THMs in most counties, higher levels occurred in winter than in summer or spring. Spatially, Yongkang, Yiwu and Dongyang had higher DBPs levels than Pujiang, Pan'an, Lanxi, Wuyi and Jinhua, which was generally consistent with their economy development (GDP). Correlation analysis showed that DBPs occurrence in tap water was significantly related with physicochemical parameters. Principle component analysis further suggested that organic matter (DOC and UVA) are the major factors influencing the occurrence of THMs, HAAs, HANs and HKs in tap water, while for HNMs, both the organic (DOC and UVA) and inorganic factors (e.g. Temp, NO-N, pH, Br and NH-N) played important role in its formation.
调查饮用水中消毒副产物(DBPs)的发生情况并确定相关影响因素对于控制 DBPs 风险至关重要。本研究采集了中国浙江省金华地区 8 个县(县级市)的 64 个自来水水样。结果表明,三卤甲烷(THMs)、卤乙酸(HAAs)、卤乙腈(HANs)、卤代酮(HKs)和卤代硝基甲烷(HNMs)的中位数(范围)分别为 23.2(9.1-40.9)、15.3(5.8-38.6)、2.2(0.7-7.6)、2.1(0.2-6.4)和 0.7(0.2-2.9)µg/L。HAAs、HANs、HKs 和 HNMs 的水平一般在夏季高于冬季或春季,而在大多数县城,THMs 的水平在冬季高于夏季或春季。从空间上看,永康、义乌和东阳的 DBPs 水平高于浦江、磐安、兰溪、武义和平湖,这与它们的经济发展(GDP)大致一致。相关性分析表明,自来水中 DBPs 的发生与理化参数显著相关。主成分分析进一步表明,有机物(DOC 和 UVA)是影响自来水中 THMs、HAAs、HANs 和 HKs 生成的主要因素,而对于 HNMs,有机物(DOC 和 UVA)和无机物(如 Temp、NO-N、pH、Br 和 NH-N)都对其形成起着重要作用。