一种方便的钯催化羰基化合成（E）-3-苄叉色满-4-酮的方法。
A Convenient Palladium-Catalyzed Carbonylative Synthesis of (E)-3-Benzylidenechroman-4-ones.
机构信息
Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, 310018, P. R. China.
Leibniz-Institut für Katalyse e.V. an der, Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
出版信息
Chemistry. 2019 Mar 7;25(14):3521-3524. doi: 10.1002/chem.201900015. Epub 2019 Feb 8.
A convenient palladium-catalyzed carbonylation reaction for the efficient synthesis of (E)-3-benzylidenechroman-4-ones has been developed. Using TFBen as a solid CO source, a range of substituted (E)-3-benzylidenechroman-4-ones were prepared in moderate to good yields with 2-iodophenols and allyl chlorides as the substrates. Additionally, substituted quinolin-4(1H)-ones can also be obtained with 2-iodoaniline as the starting material.
一种方便的钯催化羰基化反应已被开发用于高效合成(E)-3-亚苄基色满-4-酮。使用 TFBen 作为固体 CO 源，以 2-碘苯酚和烯丙基氯作为底物，可在中等至良好的产率下制备一系列取代的(E)-3-亚苄基色满-4-酮。此外，以 2-碘苯胺为起始原料，还可以得到取代的喹啉-4(1H)-酮。
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