Environmental Geochemistry Laboratory, Department of Environmental Sciences, Faculty of Biological Sciences, Quaid-i-Azam University, Islamabad, Pakistan.
Environ Monit Assess. 2019 Jan 23;191(2):95. doi: 10.1007/s10661-019-7223-8.
Present study aimed to provide a baseline data on arsenic (As) and other potentially toxic element (PTEs; Cd, Cr, Cu, Ni, and Pb) contamination in groundwater and soils (surface and sub-surface) from an industrial area of district Gujrat, Pakistan. Statistical parameters, principal component analysis-multiple linear regression (PCA-MLR), and health risk assessment model were used to elaborate the interrelations, source contributor, and associated health risks. This study revealed that the concentrations of Cd, Cr, Cu, and Pb in drinking water were within the permissible limits of the World Health Organization (WHO). However, As and Ni concentrations exceeded the WHO limits of 10 μg/L for As and 0.07 mg/L for Ni. In soils, the concentration of Cr was within permissible limits, whereas As, Cd, Cu, Ni, and Pb exceeded the prescribed values. Solid waste and industrial effluents from the area also contained high levels of As, Cd, Cr, Cu, Ni, and Pb. Calculated health index of As and other PTEs for industrial site and control area was less than 1 which indicated that the groundwater was assumed to be safe for drinking. High contamination of As (15 mg/kg) and other PTEs (Pb was 978, Cr 51, Cu 111, Cd 68, and Ni was 90 mg/kg, respectively) in upper soil could be due to the discharge of industrial effluent prior to the treatment, which signifies the industrial contribution towards As and heavy metal contamination. It can be concluded that critical examination of soil profile affinity to the respective, industrial waste pollutants can reduce the health risks to the local community. This trend not only reveals the geochemistry of the area but also useful for developing a link to access health risk and associated remediation processes.
本研究旨在为巴基斯坦古杰拉特地区一个工业区的地下水和土壤(表层和次表层)中的砷(As)和其他潜在有毒元素(PTE;Cd、Cr、Cu、Ni 和 Pb)污染提供基线数据。统计参数、主成分分析-多元线性回归(PCA-MLR)和健康风险评估模型用于阐述相互关系、来源贡献者和相关健康风险。本研究表明,饮用水中 Cd、Cr、Cu 和 Pb 的浓度均在世界卫生组织(WHO)规定的允许范围内。然而,As 和 Ni 的浓度超过了 WHO 规定的 10μg/L 的 As 和 0.07mg/L 的 Ni 限值。在土壤中,Cr 的浓度在允许范围内,而 As、Cd、Cu、Ni 和 Pb 的浓度则超过了规定值。该地区的固体废物和工业废水也含有高水平的 As、Cd、Cr、Cu、Ni 和 Pb。工业场地和对照区 As 和其他 PTE 的计算健康指数均小于 1,表明地下水可安全饮用。上层土壤中 As(15mg/kg)和其他 PTE(Pb 为 978、Cr 为 51、Cu 为 111、Cd 为 68、Ni 为 90mg/kg)的高污染可能是由于工业废水在处理前排放造成的,这表明工业对 As 和重金属污染有贡献。可以得出结论,对土壤剖面对各自工业废物污染物的亲和力进行严格检查,可以降低当地社区的健康风险。这种趋势不仅揭示了该地区的地球化学特征,而且还有助于建立联系,以获取健康风险和相关修复过程的信息。