Oxidative removal of carbamazepine by peroxymonosulfate (PMS) combined to ionizing radiation: Degradation, mineralization and biological toxicity.

Carbamazepine is one of pharmaceutical and personal care products (PPCPs) and has been widely used to treat depression and seizures, and it cannot be effectively removed during the conventional wastewater treatment processes. In this study, three processes were used for the carbamazepine degradation, including single radiation, radiation in the presence of peroxymonosulfate (PMS) and radiation followed by PMS oxidation. The results show that radiation in the presence of PMS could enhance the degradation and mineralization of carbamazepine, decreasing the absorbed dose required for completely degrading carbamazepine from 800 Gy to 300 Gy, no matter what the molar ratio of PMS to carbamazepine was. The radiation followed by PMS oxidation significantly increased the mineralization, and the maximum mineralization achieved 46.5% at the dose of 600 Gy. Eight intermediates were tentatively identified. Compared to single radiation process, the radiation in the presence of PMS enhanced the transformation of intermediates and the release of ammonium ion. In real wastewater, the radiation in the presence of PMS could effectively remove carbamazepine and considerably decreased the biological toxicity of the wastewater containing carbamazepine.