Department of Physics, Research center, JNN College of Engineering, Shivamogga, Karnataka, India.
Department of PG Studies and Research in Physics, Government Science College, Chitradurga, Karnataka, India.
Talanta. 2019 May 1;196:337-344. doi: 10.1016/j.talanta.2018.12.072. Epub 2018 Dec 24.
The humidity sensing performance of Polyaniline/Water soluble graphene oxide [PWGO] composites have been presented in this work. Various mass ratios of Water soluble graphene oxide [WGO] were mechanically mixed with Polyaniline [PANI] prepared by in-situ polymerization process to form PANI / WGO composites. For the purpose of humidity sensing studies, the samples were structurally characterized by FTIR, Raman, XRD, SEM and TEM techniques and comparatively analyzed. The film of the samples prepared by deposition on ordinary glass substrate using cost effective spin coating technique were tested for their humidity sensing performance in the relative humidity (RH) range of 11-97%. Of the four composites studied, the PWGO-4 composite recorded a good response time of 8 s and a recovery time of 9 s and a very low humidity hysteresis. The mechanism for sensing has been explained on the basis of three sequential steps: chemisorption, physisorption and condensation process. The humidity sensing stability of the composites were tested over a period of 2 months.
本文介绍了聚苯胺/水溶性氧化石墨烯[PWGO]复合材料的湿度传感性能。通过机械混合的方法将不同质量比的水溶性氧化石墨烯[WGO]与原位聚合制备的聚苯胺[PANI]复合,形成 PANI/WGO 复合材料。为了进行湿度传感研究,采用傅里叶变换红外光谱(FTIR)、拉曼光谱(Raman)、X 射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等结构表征技术对样品进行了比较分析。采用成本效益高的旋涂技术将样品沉积在普通玻璃基底上制备薄膜,在相对湿度(RH)为 11%至 97%的范围内测试其湿度传感性能。在所研究的四种复合材料中,PWGO-4 复合材料的响应时间为 8s,恢复时间为 9s,湿度滞后非常低,表现出良好的性能。基于三个连续步骤:化学吸附、物理吸附和凝结过程,解释了传感机制。对复合材料的湿度传感稳定性进行了为期 2 个月的测试。