Wang Dan, Zhao Gang, Chen Chunhao, Zhang Hui, Duan Ruomeng, Zhang Dafeng, Li Mingtong, Dong Bin
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices , Soochow University , Suzhou , Jiangsu 215123 , P. R. China.
School of Environment and Civil Engineering , Dongguan University of Technology , Dongguan 523808 , P. R. China.
Langmuir. 2019 Feb 19;35(7):2801-2807. doi: 10.1021/acs.langmuir.8b02904. Epub 2019 Feb 11.
In this paper, we report a novel multi-responsive walnut-like micromotor consisting of polycaprolactone (PCL), iron oxide nanoparticles (FeO NPs), and catalase, which is constructed through a one-step electrospinning method. Based on the catalytic activity and photothermal and magnetic responsiveness originating from catalase and FeO NPs, respectively, the resulting micromotor exhibits an autonomous movement in the presence of hydrogen peroxide (HO) fuel, controlled motion velocity under light irradiation, and guided movement direction upon the application of an external magnetic field. Owing to the hydrophobic nature of the PCL polymer constituent inside the micromotor, the autonomous moving micromotor can collect spilled oil inside a solution once it collides with the oil droplet. Since the micromotor could be separated out using a magnetic field, we believe the current walnut-like micromotor holds great promise in the field of environmental remediation.
在本文中,我们报道了一种新型的多响应核桃状微马达,它由聚己内酯(PCL)、氧化铁纳米颗粒(FeO NPs)和过氧化氢酶组成,通过一步电纺丝法构建而成。基于分别源自过氧化氢酶和FeO NPs的催化活性以及光热和磁响应性,所得微马达在过氧化氢(HO)燃料存在下表现出自主运动,在光照下运动速度可控,在施加外部磁场时运动方向可被引导。由于微马达内部PCL聚合物成分的疏水性,自主移动的微马达一旦与油滴碰撞,就能收集溶液中的溢油。由于该微马达可以通过磁场分离出来,我们相信当前的核桃状微马达在环境修复领域具有巨大的潜力。