Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China , Heilongjiang University , Harbin 150080 , P. R. China.
ACS Appl Mater Interfaces. 2019 Feb 20;11(7):7066-7073. doi: 10.1021/acsami.8b20665. Epub 2019 Feb 8.
Using solar energy to achieve seawater desalination and sewage disposal has received tremendous attention for its potential possibility to produce clean freshwater. However, the low solar-thermal conversion efficiency for solar absorber materials obstacles their practical applications. Herein, Ag nanoparticles modified floating carbon cloth (ANCC) are first synthesized via wet impregnation, photoreduction, and low-temperature drying strategy, which could float on the water and absorb the solar energy efficiently. It is worth noting that vaporization rate of ANCC with a high wide-spectrum absorption (92.39%) for the entire range of optical spectrum (200-2500 nm) is up to 1.36 kg h m under AM 1.5, which corresponds to solar-thermal conversion efficiency of ∼92.82% with superior seawater desalination and sewage disposal performance. Plasmon Ag promotes the conversion efficiency obviously compared to the pristine carbon cloth because the surface plasmon resonance effect could increase the local temperature greatly. After the desalination, the ion concentrations (Mg, K, Ca, and Na ions) in water are far below the limit of drinking water. Such high-performance floating ANCC material may offer a feasible and paradigm strategy to manage the global water contamination and freshwater shortage problem.
利用太阳能实现海水淡化和污水处理因其生产清洁淡水的潜在可能性而受到极大关注。然而,太阳能吸收材料的低太阳能-热转换效率阻碍了它们的实际应用。在此,通过湿浸渍、光还原和低温干燥策略首次合成了 Ag 纳米颗粒修饰的漂浮碳纤维布(ANCC),它可以高效地漂浮在水面上并吸收太阳能。值得注意的是,具有整个光学光谱范围(200-2500nm)高宽谱吸收(92.39%)的 ANCC 的蒸发率高达 1.36kg h m-2 在 AM 1.5 下,对应于约 92.82%的太阳能-热转换效率,并具有优异的海水淡化和污水处理性能。与原始碳纤维布相比,等离子体 Ag 明显促进了转化效率,因为表面等离子体共振效应可以大大提高局部温度。在海水淡化后,水中的离子浓度(Mg、K、Ca 和 Na 离子)远低于饮用水的限值。这种高性能的漂浮 ANCC 材料可能为解决全球水污染和淡水短缺问题提供了一种可行的范例策略。