基于含席夫碱的柱芳烃的线性 AIE 超分子聚合物及其通过 Cu 和氰根的可逆交联。
A Linear AIE Supramolecular Polymer Based on a Salicylaldehyde Azine-Containing Pillararene and Its Reversible Cross-Linking by Cu and Cyanide.
机构信息
Ministry of Education Key Laboratory of Interface Science and Engineering in Advanced Materials, Research Center of Advanced Materials Science and Technology , Taiyuan University of Technology , Taiyuan 030024 , P. R. China.
Scientific Instrument Center , Shanxi University , Taiyuan 030006 , P. R. China.
出版信息
Inorg Chem. 2019 Feb 18;58(4):2252-2256. doi: 10.1021/acs.inorgchem.8b02896. Epub 2019 Jan 29.
A linear AIE supramolecular polymer was constructed by a salicylaldehyde azine-containing pillar[5]arene dimer P5D and a homoditopic guest G. The linear supramolecular polymer displayed strong fluorescence at high concentration. It displayed cross-linked structure and fluorescence quenching property after the addition of Cu and recovered after the addition of cyanide.
通过含有席夫碱的柱[5]芳烃二聚体 P5D 和一个同双客体 G 构建了一种线性 AIE 超分子聚合物。该线性超分子聚合物在高浓度下显示出强荧光。加入 Cu 后，其呈现交联结构和荧光猝灭性质，加入氰化物后可恢复。
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