Laboratoire de Physique de l'École Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université Paris-Diderot, Sorbonne Paris Cité, UMR CNRS 8550, 24 rue Lhomond, F-75005 Paris, France.
Nanotechnology. 2019 May 10;30(19):195502. doi: 10.1088/1361-6528/ab02ba. Epub 2019 Jan 29.
Surface force apparatus (SFA) allows accurate resolving of the interfacial properties of fluids confined between extended surfaces. The accuracy of the SFA makes it an ubiquitous tool for the nanoscale mechanical characterization of soft matter systems. The SFA traditionally measures force-distance profiles through interferometry with subnanometric distance precision. However, these techniques often require a dedicated and technically demanding experimental setup, and there remains a need for versatile and simple force-distance measurement tools. Here we present a MicroMegascope based dynamic SFA capable of accurate measurement of the dynamic force profile of a liquid confined between a millimetric sphere and a planar substrate. Normal and shear mechanical impedance is measured within the classical frequency modulation framework. We measure rheological and frictional properties from micrometric to molecular confinement. We also highlight the resolution of small interfacial features such as ionic liquid layering. This apparatus shows promise as a versatile force-distance measurement device for exotic surfaces or extreme environments.
表面力仪器 (SFA) 可准确解析扩展表面之间受限流体的界面特性。SFA 的准确性使其成为软物质系统纳米级机械特性分析的通用工具。SFA 传统上通过亚纳米距离精度的干涉测量来测量力-距离曲线。然而,这些技术通常需要专用且技术要求高的实验设置,因此仍然需要多功能且简单的力-距离测量工具。在这里,我们展示了一种基于 MicroMegascope 的动态 SFA,它能够精确测量毫米级球体和平面基底之间受限液体的动态力曲线。在经典的调频框架内测量法向和剪切力学阻抗。我们在从微米到分子的约束范围内测量流变学和摩擦特性。我们还强调了对小界面特征(如离子液体分层)的分辨率。该仪器有望成为用于特殊表面或极端环境的多功能力-距离测量设备。