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用于光通信的压电-光电子增强锯齿状结构 ZnO 基异质结光电探测器。

A piezo-phototronic enhanced serrate-structured ZnO-based heterojunction photodetector for optical communication.

机构信息

Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China.

出版信息

Nanoscale. 2019 Feb 7;11(6):3021-3027. doi: 10.1039/c8nr09418g.

Abstract

ZnO-based heterojunction photodetectors have been widely used in various fields such as optical imaging and health monitoring. As for the traditional planar heterojunction interface, their limited optical absorption will place restrictions on the full photoelectric potential of ZnO nanorods, which severely restrains the commercial applications of ZnO-based photodetectors. Herein, using an intrinsically octahedral structure of p-type Cu2O and one-dimensional ZnO arrays, the newly designed serrate-structured heterojunction was constructed, whose unique serrate-structured interface of ZnO/Cu2O is highly conducive to the aggrandizing of optical absorption. The as-fabricated photodetector could achieve a high on/off ratio up to 1000 and an optimum photocurrent of 24.90 μA under 1.41 mW mm-2 (405 nm) illumination without bias voltage, which was 2.5 times higher than that of the planar-structured photodetector, and the response time was as quick as 1.6 ms. When the additional external strain was 0.39%, the performance was dramatically enhanced more than 5 times due to the synergism of the piezo-phototronic effect and the serrate-structured design. Based on this, we successfully developed designed photodetector arrays with an excellent optical communication performance of transmitting information. Prospectively, this kind of unique serrate-structured heterojunction design will open up a possible opportunity for high performance photodetectors based on structural engineering.

摘要

基于 ZnO 的异质结光电探测器已经在光学成像和健康监测等多个领域得到广泛应用。对于传统的平面异质结界面,其有限的光学吸收将限制 ZnO 纳米棒的全光电势,这严重限制了基于 ZnO 的光电探测器的商业应用。在此,我们利用 p 型 Cu2O 的本征八面体结构和一维 ZnO 阵列,构建了新设计的锯齿状结构异质结,其独特的 ZnO/Cu2O 锯齿状界面非常有利于光学吸收的增强。所制备的光电探测器在没有偏置电压的情况下,在 1.41 mW mm-2(405nm)光照下,实现了高达 1000 的高开关比和 24.90 μA 的最佳光电流,比平面结构光电探测器高 2.5 倍,响应时间快至 1.6 ms。当外加应变为 0.39%时,由于压光电效应和锯齿状设计的协同作用,性能显著增强了 5 倍以上。在此基础上,我们成功地开发了具有优异光通信性能的设计型光电探测器阵列,可用于传输信息。有前景的是,这种独特的锯齿状结构异质结设计将为基于结构工程的高性能光电探测器开辟一条可能的途径。

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