可见光促进二硒醚与烯烃的有氧硒化反应制备杂环化合物。
Preparation of Heterocycles via Visible-Light-Driven Aerobic Selenation of Olefins with Diselenides.
机构信息
State Key Laboratory of Applied Organic Chemistry , Lanzhou University , 222 South Tianshui Road , Lanzhou 730000 , P. R. China.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry , the Chinese Academy of Sciences , Beijing 100190 , P. R. China.
出版信息
Org Lett. 2019 Feb 15;21(4):885-889. doi: 10.1021/acs.orglett.8b03738. Epub 2019 Jan 30.
The aerobic dehydrogenative cyclization of alkenes with easily accessible diselenides facilitated by visible light is reported. Notably, the features of this transition-metal-free protocol are pronounced efficiency and practicality, good functional group tolerance, atom economy, and high sustainability, since ambient air and visible light are adequate for the clean construction of five- and six membered heterocycles in yields of up to 98%.
报告了可见光促进的烯烃与易得二硒醚的有氧脱氢环化反应。值得注意的是，该无金属过渡方案的特点是效率高、实用性强、官能团耐受性好、原子经济性高、可持续性好，因为环境空气和可见光足以在高达 98%的收率下清洁构建五元和六元杂环。
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