Metakaolinite Phosphate Cementitious Matrix: Inorganic Polymer Obtained by Acidic Activation.

This work aims to study an aluminosilicate phosphate cementitious matrix. The cementitious matrix was studied on paste samples. The synthesis of metakaolinite phosphate cement (MKPC) was investigated using calorimetric techniques. A systematic study was performed by emphasizing a broad range of Al/P molar ratios, covering the different behavior of the material to the extremes, as well as the optimum composition. X-ray diffraction and scanning electron microscopy revealed that the final structure was mainly an amorphous network, albeit with some non-reacted phases. The compressive strength was studied on mortars using a cement/sand ratio of 1:3. MKPC specimens with Al/P ratios close to 1/1 showed optimal behavior. MKPCs with Al/P ratios above 1/1 were characterized by high porosity and low strength, whereas MKPCs with Al/P < 1 contained an excess of phosphates. The influence of the Al/P molar ratio on compressive strength was also studied, reaching a maximum of 68 MPa for the optimum composition. Based on the results, MKPC may be a promising candidate for construction purposes.