通过铂和钯掺杂提高铜交换丝光沸石在甲烷直接等温转化为甲醇中的活性。
Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping.
作者信息
Tomkins P, Mansouri A, L Sushkevich V, van der Wal L I, Bozbag S E, Krumeich F, Ranocchiari M, van Bokhoven J A
机构信息
Paul Scherrer Institut , CH-5232 Villigen , Switzerland.
ETH Zurich , Wolfgang-Pauli-Strasse 10 , CH-8093 Zurich , Switzerland . Email:
出版信息
Chem Sci. 2018 Oct 3;10(1):167-171. doi: 10.1039/c8sc02795a. eCollection 2019 Jan 7.
Abstract
PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation.
摘要
PtCu和PdCu丝光沸石能在200℃下实现等温反应，用于甲烷逐步转化为甲醇，产率相对较高。与传统的铜沸石相比，这些材料在等温条件下比高温活化后更具反应活性。
Zotero 插件