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利用糖能产业副产物制备水凝胶:萃取液对营养物质和有机碳释放的影响研究。

Hydrochars produced with by-products from the sucroenergetic industry: a study of extractor solutions on nutrient and organic carbon release.

机构信息

Departamento de Química e Ciências Ambientais, Laboratório de Estudos em Ciências Ambientais, Instituto de Biociências, Letras e Ciências Exatas, UNESP, Universidade Estadual Paulista, Campus São José do Rio Preto, Cristóvão Colombo, 2265, São José do Rio Preto, São Paulo State, 15054-000, Brazil.

Laboratório de Materiais Funcionais Avançados (LaMFA), Departamento de Física, Universidade Federal do Ceará, P.O. Box 6030, Fortaleza, Ceará, 60455-900, Brazil.

出版信息

Environ Sci Pollut Res Int. 2019 Mar;26(9):9137-9145. doi: 10.1007/s11356-019-04341-9. Epub 2019 Feb 4.

DOI:10.1007/s11356-019-04341-9
PMID:30715701
Abstract

Hydrothermal carbonization transforms biomass into value-added material called hydrochar. The release of nutrients (P, N, Ca, Mg, and K) and organic carbon (TOC) from hydrochar in different extractive solutions was investigated in this study. Two sets of hydrochar were produced: (i) hydrochar prepared from sugarcane bagasse and vinasse mixture (BV-HC) and (ii) hydrochar prepared by the addition of HPO to this mixture (BVA-HC). Both hydrochar types released significative amounts of nutrient and organic carbon, mainly Ca (5.0 mg g) in the mixture (KCl, KSO, NaOH, 1:1:1) extractive solution and TOC (72.6 mg g) in the NaOH extractive solution, for BV-HC. Nutrient release was influenced by pH and ionic strength. The release of P, Ca, and Mg was affected by the presence of insoluble phosphate phases in BVA-HC. The release of nutrients P, N, Ca, Mg, and K and organic carbon demonstrated that hydrochar has potential for soil application purposes.

摘要

水热碳化将生物质转化为称为水炭的增值材料。本研究考察了不同提取溶液中来自水炭的养分(P、N、Ca、Mg 和 K)和有机碳(TOC)的释放。制备了两组水炭:(i)由甘蔗渣和酒糟混合物制备的水炭(BV-HC)和(ii)通过向该混合物中添加 HPO 制备的水炭(BVA-HC)。两种水炭类型都释放出大量的营养物质和有机碳,主要是 Ca(5.0mg g)在混合提取溶液(KCl、KSO、NaOH,1:1:1)和 TOC(72.6mg g)在 NaOH 提取溶液中,对于 BV-HC。养分释放受 pH 值和离子强度的影响。BVA-HC 中不溶性磷酸盐相的存在影响 P、Ca 和 Mg 的释放。养分 P、N、Ca、Mg 和 K 的释放以及有机碳表明水炭具有用于土壤应用的潜力。

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本文引用的文献

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Toxicity evaluation of process water from hydrothermal carbonization of sugarcane industry by-products.水热碳化甘蔗工业副产物工艺水的毒性评价。
Environ Sci Pollut Res Int. 2019 Sep;26(27):27579-27589. doi: 10.1007/s11356-018-1771-2. Epub 2018 Mar 29.
2
Phosphorus recovery and reuse by pyrolysis: Applications for agriculture and environment.热解法回收和再利用磷:在农业和环境中的应用。
Chemosphere. 2018 Mar;194:682-691. doi: 10.1016/j.chemosphere.2017.12.035. Epub 2017 Dec 7.
3
Phosphorus speciation and release kinetics of swine manure biochar under various pyrolysis temperatures.
不同热解温度下猪粪生物炭中磷的形态和释放动力学。
Environ Sci Pollut Res Int. 2018 Sep;25(26):25780-25788. doi: 10.1007/s11356-017-0640-8. Epub 2017 Nov 21.
4
Biochar as an adsorbent for inorganic nitrogen and phosphorus removal from water: a review.生物炭作为一种从水中去除无机氮磷的吸附剂:综述。
Environ Sci Pollut Res Int. 2017 Dec;24(34):26297-26309. doi: 10.1007/s11356-017-0338-y. Epub 2017 Oct 14.
5
In-depth characterization of valuable char obtained from hydrothermal conversion of hazelnut shells to levulinic acid.深入研究榛子壳水热转化制备乙酰丙酸过程中得到的有价值炭的特性。
Bioresour Technol. 2017 Nov;244(Pt 1):880-888. doi: 10.1016/j.biortech.2017.08.012. Epub 2017 Aug 7.
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Effect of the reaction medium on the immobilization of nutrients in hydrochars obtained using sugarcane industry residues.反应介质对利用甘蔗工业残渣制备的水热炭中养分固定化的影响。
Bioresour Technol. 2017 Aug;237:213-221. doi: 10.1016/j.biortech.2017.04.004. Epub 2017 Apr 4.
7
Mechanisms of metal sorption by biochars: Biochar characteristics and modifications.生物炭对金属的吸附机制:生物炭特性与改性
Chemosphere. 2017 Jul;178:466-478. doi: 10.1016/j.chemosphere.2017.03.072. Epub 2017 Mar 24.
8
Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions.水溶液中重金属离子在芝麻秸秆生物炭上的竞争吸附
Chemosphere. 2016 Jan;142:77-83. doi: 10.1016/j.chemosphere.2015.05.093. Epub 2015 Jun 14.
9
Nitrogen enrichment potential of biochar in relation to pyrolysis temperature and feedstock quality.生物炭的热解温度和原料质量与氮素富集潜力的关系。
J Environ Manage. 2015 Apr 1;152:140-4. doi: 10.1016/j.jenvman.2015.01.021. Epub 2015 Jan 23.
10
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J Environ Manage. 2015 Feb 1;149:9-16. doi: 10.1016/j.jenvman.2014.09.033. Epub 2014 Oct 17.