Department of Industrial Chemistry "Toso Montanari", Alma Mater Studiorum-University of Bologna, viale del Risorgimento 4, 40136, Bologna, Italy.
Chem Rec. 2019 Oct;19(10):2095-2104. doi: 10.1002/tcr.201800194. Epub 2019 Feb 7.
The enantioselective synthesis of atropisomers is an emerging field, that in recent years reached fundamental results and put the bases for innovative applications. Organocatalysis is playing a central role in the realization of original synthesis for novel atropisomeric scaffolds. In this short review, we would like to highlight the results obtained by our group and others in the field of axially enantioselective desymmetrization reactions using organocatalysis as main strategy.
对映异构体的对映选择性合成是一个新兴领域，近年来取得了重要成果，并为创新应用奠定了基础。有机催化在实现新型轴手性骨架的原始合成中发挥着核心作用。在这篇简短的综述中，我们想强调我们小组和其他小组在使用有机催化作为主要策略的轴手性去对称化反应中获得的结果。
