Wang Xiaofeng, Guo Haoyan, Yang Bo, Chang Xingwen, Wan Chenguang, Wang Zhenjun
Research and Development Center of Transport Industry of Technologies, Materials and Equipments of Highway Construction and Maintenance, Zhengzhou 450052, China.
Henan Engineering Research Center of Intelligent Highway Big Data, Zhengzhou 450052, China.
Materials (Basel). 2019 Feb 10;12(3):530. doi: 10.3390/ma12030530.
The aging of bitumen seriously affects the service life of bituminous pavements. At present, there are many related researches on bitumen aging, but most of them focus on aging endured in indoor surroundings and conditions. Therefore, the conclusions obtained cannot reflect the actual aging changes of bitumen in bituminous pavements in service. In order to study the comprehensive aging process and mechanism of bitumen under the influence of service, we studied bridge deck, traffic lane, and ramp with bituminous pavement structures in service. The bitumen samples obtained from the core samples in different bituminous pavement structures were characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR), dynamic shear rheometer (DSR), and fluorescence microscope (FM). The aging degree of different bitumen was analyzed, and conclusions were drawn on changes to bitumen aging from different pavement structures. The results showed that the aging degree of bitumen from the upper layer was the most serious, the aging degree of bitumen at the middle layer was weaker than that of bitumen from the upper layer, and the aging degree of bitumen from the bottom layer was the weakest for the different bituminous pavement structures. The aging of bitumen mainly occurred due to oxygen absorption. After aging, viscoelastic components of bitumen changed, and bitumen became harder. The macromolecule of bitumen could be divided into small molecules, and the small molecular weight of bitumen became large. The styrene-butadiene-styrene (SBS) modifier in the modified bitumen became granular after aging, and it appeared as a single phase in bitumen. The aging changes characterized by different analytical methods showed that the aging degree of bitumen from different layers of bituminous pavement structures in service was different. Effective measures should therefore be taken in time to decrease further aging of bitumen from the upper layer of bituminous pavements due to its inevitable early aging in service.
沥青老化严重影响沥青路面的使用寿命。目前,关于沥青老化已有许多相关研究,但大多集中在室内环境和条件下的老化情况。因此,所得结论无法反映实际服役中沥青路面中沥青的老化变化。为研究服役影响下沥青的综合老化过程及机理,我们对现役沥青路面结构的桥面、行车道和匝道进行了研究。从不同沥青路面结构的芯样中获取的沥青样品,采用凝胶渗透色谱法(GPC)、傅里叶变换红外光谱法(FTIR)、动态剪切流变仪(DSR)和荧光显微镜(FM)进行表征。分析了不同沥青的老化程度,并得出不同路面结构沥青老化变化的结论。结果表明,对于不同的沥青路面结构,上层沥青的老化程度最严重,中层沥青的老化程度弱于上层沥青,下层沥青的老化程度最弱。沥青老化主要是由于吸氧所致。老化后,沥青的粘弹性成分发生变化,沥青变硬。沥青大分子可分解为小分子,且沥青的小分子分子量增大。改性沥青中的苯乙烯 - 丁二烯 - 苯乙烯(SBS)改性剂老化后呈颗粒状,在沥青中呈单相出现。不同分析方法表征的老化变化表明,现役沥青路面结构不同层位的沥青老化程度不同。因此,鉴于上层沥青在服役中不可避免地会早期老化,应及时采取有效措施,减少沥青路面上层沥青的进一步老化。