可见光促进的 N-丙炔基苯胺与亚磺酸的氧化环化反应，无需外加光催化剂即可生成 3-磺化喹啉衍生物。
A visible-light-induced oxidative cyclization of N-propargylanilines with sulfinic acids to 3-sulfonated quinoline derivatives without external photocatalysts.
机构信息
Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
出版信息
Chem Commun (Camb). 2019 Feb 28;55(19):2785-2788. doi: 10.1039/c8cc10235j.
PMID:30758355
Abstract
A visible-light-induced oxidative cyclization of N-propargyl anilines with sulfinic acids was developed under external photocatalyst-free conditions. The reaction provides a straightforward route to 3-sulfonated quinoline derivatives with good functional group tolerance, excellent yields and high regio-selectivity.
摘要
发展了一种在无外加光催化剂条件下，通过 N-丙炔基苯胺与亚磺酸的可见光诱导氧化环化反应。该反应为 3-磺酸基喹啉衍生物提供了一条具有良好官能团耐受性、高产率和高区域选择性的直接途径。
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