掺镱氧化锌花状基苯腙化学传感器。
Ytterbium-Doped ZnO Flowers Based Phenyl Hydrazine Chemical Sensor.
机构信息
Department of Physics, Faculty of Sciences, King Abdulaziz University, Jeddah-21589, Kingdom of Saudi Arabia.
Department of Chemistry, Faculty of Science and Arts, Najran University, P.O. Box 1988, Najran-11001, Kingdom of Saudi Arabia.
出版信息
J Nanosci Nanotechnol. 2019 Jul 1;19(7):4199-4204. doi: 10.1166/jnn.2019.16283.
Herein, we report the fabrication and characterization of phenyl hydrazine sensor based on ytterbium (Yb) doped ZnO flowers composed of nanorods prepared by simple hydrothermal process. The as-synthesized nanomaterial was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) attached with energy dispersive spectroscopy (EDS), Fourier transformation infrared (FTIR) and Raman-scattering spectroscopy which revealed the large-quantity synthesis, well-crystallinity and wurtzite hexagonal crystal structure of Yb-doped ZnO flowers. The fabricated phenyl hydrazine chemical sensor, by employing Yb-doped ZnO flowers as an electron mediator, exhibited sensitivity of ∼34.2 A·mM ·cm, detection limit of 24 mM and linear dynamic range of 0.25-4.0 mM. The presented work demonstrates that the Yb-doped ZnO nanomaterials are promising electron mediator which can be used for the fabrication of chemical sensors to detect various hazardous and toxic chemicals as phenyl hydrazine.
本文报道了通过简单的水热法制备的由纳米棒组成的掺镱氧化锌（Yb）花状结构，用于苯肼传感器的制造和特性研究。通过 X 射线衍射（XRD）、场发射扫描电子显微镜（FESEM）和能量色散谱（EDS）、傅里叶变换红外（FTIR）和拉曼散射光谱对合成的纳米材料进行了表征，结果表明Yb 掺杂 ZnO 花状结构具有大量合成、良好结晶和纤锌矿六方晶体结构。所制备的苯肼化学传感器，采用 Yb 掺杂 ZnO 花状结构作为电子介体，表现出约 34.2 A·mM ·cm 的灵敏度、24 mM 的检测限和 0.25-4.0 mM 的线性动态范围。本工作表明，Yb 掺杂 ZnO 纳米材料是一种很有前途的电子介体，可用于制造化学传感器来检测各种危险和有毒化学物质，如苯肼。
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