Narasimman S, Balakrishnan L, Alex Z C
School of Electronics Engineering, VIT Vellore 632 014 India
Department of Physics, Government College of Technology Coimbatore 641 013 India
RSC Adv. 2018 May 18;8(33):18243-18251. doi: 10.1039/c8ra01803k. eCollection 2018 May 17.
A fiber optic magnetic field sensor is proposed and experimentally demonstrated. Pristine and Co doped ZnO nanorods of different Co concentrations (5, 10, 15 and 20 at%) were synthesized using a hydrothermal method. The synthesized nanorods were subjected to various characterization methods like X-ray diffraction (XRD), optical absorption, scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, vibrating sample magnetometry and X-ray photoelectron spectroscopy (XPS). XRD and XPS analysis confirms that the Co ions were successfully incorporated into the Zn site of the wurtzite ZnO lattice without altering the structure. The pristine and Co doped ZnO nanorods showed remarkable changes in the - loop where the diamagnetic behavior of ZnO changes to paramagnetic when doped with Co. The sensor structure is composed of cladding modified fiber coated with Co doped ZnO nanorods as a sensing material. The modified cladding is proportionally sensitive to the ambient magnetic field because of the magneto-optic effect. Experimental results revealed that the sensor has an operating magnetic field range from 17 mT to 180 mT and shows a maximum sensitivity of ∼18% for 15 at% Co doped ZnO nanorods. The proposed magnetic field sensor would be attractive due to its low cost fabrication, simplicity of the sensor head preparation, high sensitivity and reproducibility.
提出并通过实验演示了一种光纤磁场传感器。采用水热法合成了不同钴浓度(5%、10%、15%和20%原子分数)的原始及钴掺杂氧化锌纳米棒。对合成的纳米棒进行了多种表征方法,如X射线衍射(XRD)、光吸收、扫描电子显微镜、能量色散X射线光谱、傅里叶变换红外光谱、振动样品磁强计和X射线光电子能谱(XPS)。XRD和XPS分析证实,钴离子成功地掺入到纤锌矿型氧化锌晶格的锌位点中,而不改变其结构。原始及钴掺杂氧化锌纳米棒在磁滞回线中表现出显著变化,其中氧化锌的抗磁行为在掺杂钴后变为顺磁行为。传感器结构由涂覆有钴掺杂氧化锌纳米棒作为传感材料的包层改性光纤组成。由于磁光效应,改性包层对周围磁场成比例敏感。实验结果表明,该传感器的工作磁场范围为17 mT至180 mT,对于15%原子分数钴掺杂的氧化锌纳米棒,最大灵敏度约为18%。所提出的磁场传感器因其低成本制造、传感器头制备简单、高灵敏度和可重复性而具有吸引力。