Influence of Sensitization on Mechanical Properties of AISI 304 Stainless Steel under High-Temperature.

This study investigated influence of sensitization on the mechanical properties of AISI 304 stainless steel. The small and tensile specimens were isothermally aged at 650 °C for up to 1000 hours. Microstructure and precipitates of these specimens were characterized by scanning electrode microscope with energy dispersive X-ray spectroscopy. The degree of sensitization of aged specimens was measured by double loop electrochemical potentiodynamic reactivation method. The tensile test was conducted to evaluate mechanical properties of these specimens. With the progress of aging, the degree of sensitization value drastically increased to more than 50% as Cr-rich carbides were precipitated in the austenite grain boundaries. Also, the mechanical properties were degraded, and fracture mode drastically changed from ductile to brittle. As a result, the surface damage and degradation of mechanical properties were correlated with the degree of sensitization value.