Popoola Lekan Taofeek
Unit Operation and Material Science Research Laboratory, Chemical and Petroleum Engineering Department, Afe Babalola University, Ekiti State, Nigeria.
Heliyon. 2019 Feb 1;5(2):e01143. doi: 10.1016/j.heliyon.2019.e01143. eCollection 2019 Feb.
In the past, lives and wealth have been lost due to corrosion in almost all engineering fields. Not only this, the cost of reviving damaged equipments in the industry due to corrosion contributed a lot to the gross domestic product of a nation. Thus, all hands must be on desk to combat this harzadous act via time to time research on its final resolution. However, current research works have revealed effective and reliable corrosion inhibitors from pharmaceutical drugs, plant extracts and ionic liquids as organic green corrosion inhibitors (OGCIs) with accommodative attributes such as being environmentally friendly, readily available, biodegradable, non-harmful, relatively cheap and many others to mention a few. This paper opens readers mind into the detailed classifications, mechanisms and active functional groups of these eco-friendly OGCIs. Not only the corrosion efficiency calculation ways but also influencing factors on efficiency were presented. Plant extracts, pharmaceutical drugs, ionic liquids and synthetic inhibitors, as among major sources of OGCIs, used in preventing material corrosion in corrosive media were separately and comprehensively examined. The significance of values obtained from simulating presented mathematical models governing OGCIs kinetics, adsorption isotherm and adsorption thermodynamics was also included. In conclusion, beneficial recommendations for both current and prospective researchers in the field of Corrosion Engineering were presented.
过去,几乎在所有工程领域,腐蚀都曾导致人员伤亡和财富损失。不仅如此,工业中因腐蚀而修复受损设备的成本对一个国家的国内生产总值贡献巨大。因此,必须齐心协力,通过对其最终解决方案的不断研究来对抗这种有害行为。然而,目前的研究工作已经揭示了来自药物、植物提取物和离子液体的有效且可靠的缓蚀剂,它们作为有机绿色缓蚀剂(OGCIs),具有诸如环保、易于获取、可生物降解、无害、相对便宜等诸多适应性特性。本文向读者详细介绍了这些环保型OGCIs的分类、作用机制和活性官能团。不仅介绍了腐蚀效率的计算方法,还阐述了影响效率的因素。分别并全面地研究了植物提取物、药物、离子液体和合成缓蚀剂作为OGCIs的主要来源在防止腐蚀介质中材料腐蚀方面的应用。还包括了从模拟控制OGCIs动力学、吸附等温线和吸附热力学的数学模型中获得的值的意义。总之,针对腐蚀工程领域的当前和未来研究人员提出了有益的建议。