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从细菌纤维素中获得的气凝胶的物理和机械性能研究。

A Study of the Physical and Mechanical Properties of Aerogels Obtained from Bacterial Cellulose.

机构信息

National Research Ogarev Mordovia State University , Saransk 430005 , Russia.

Samara National Research University , Samara 443086 , Russia.

出版信息

Biomacromolecules. 2019 Mar 11;20(3):1401-1411. doi: 10.1021/acs.biomac.8b01816. Epub 2019 Feb 26.

Abstract

Aerogels with a density of 4.2-22.8 kg/m were obtained from bacterial cellulose synthesized under static and dynamic cultivation conditions on a molasses medium. The strength properties and porous structure of the aerogels strongly depended on their density. With an aerogel density of 22.8 kg/m, the modulus of elasticity at 80% compression of the sample was 0.1 MPa. The decrease in the density of aerogels led to an increase in the pore sizes ranging from 20 to 1000 μm and a decrease in the modulus of elasticity. These characteristics were more pronounced in aerogels obtained from bacterial cellulose under static cultivation conditions. The aerogels had a low coefficient of thermal conductivity (0.0257 W m °C), which is comparable to the thermal conductivity of air, and moderate thermal stability because the degradation processes of the aerogels began at 237 °C. The aerogels obtained from bacterial cellulose had high sound absorption coefficients in the frequency range of 200-5000 Hz, which makes it possible to use the aerogels as heat- and sound-insulating materials.

摘要

采用静态和动态培养条件在糖蜜培养基上合成的细菌纤维素制备了密度为 4.2-22.8kg/m 的气凝胶。气凝胶的强度性能和多孔结构强烈依赖于其密度。当气凝胶的密度为 22.8kg/m 时,样品在 80%压缩时的弹性模量为 0.1MPa。气凝胶密度的降低导致孔径从 20 到 1000μm 增加,弹性模量降低。在静态培养条件下获得的细菌纤维素气凝胶中,这些特征更为明显。气凝胶的导热系数(0.0257Wm°C)较低,与空气的导热系数相当,且具有适度的热稳定性,因为气凝胶的降解过程始于 237°C。由细菌纤维素获得的气凝胶在 200-5000Hz 的频率范围内具有较高的吸声系数,这使得气凝胶可用作隔热和隔音材料。

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