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可见光照耀下 Ag@有机分子笼催化的硝基芳烃选择性还原为偶氮化合物。

Visible-light triggered selective reduction of nitroarenes to azo compounds catalysed by Ag@organic molecular cages.

机构信息

College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, China.

出版信息

Chem Commun (Camb). 2019 Mar 21;55(25):3586-3589. doi: 10.1039/c8cc10078k.

DOI:10.1039/c8cc10078k
PMID:30775727
Abstract

Herein, a new Ag nanoparticle (Ag NP) loaded organic molecular cage is reported. The obtained Ag@1 can act as a highly efficient heterogeneous catalyst for the selective reduction of nitroarenes to azo compounds under visible-light irradiation.

摘要

本文报道了一种新型的负载有银纳米颗粒(Ag NP)的有机分子笼。所得到的 Ag@1 可以在可见光照射下作为一种高效的多相催化剂,用于选择性还原硝基芳烃为偶氮化合物。

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