从有机-无机[2]轮烷形成互锁双链。

Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane.

机构信息

School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.

出版信息

Chem Commun (Camb). 2019 Mar 5;55(20):2960-2963. doi: 10.1039/c8cc09339c.

Abstract

Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic-organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3].

摘要

在这里，我们展示了一种结构，该结构是通过无机-有机[2]轮烷[HB{CrIII7NiII(μ-F)8(O2CtBu)16}]与氧中心金属羧酸三角形[FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3]的反应得到的，其中 B 是末端带有双吡啶单元的有机线。