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烯烃复分解反应在功能化多面体低聚倍半硅氧烷（POSS）及含POSS聚合物材料合成中的应用。

Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials.

作者信息

Żak Patrycja, Pietraszuk Cezary

机构信息

Adam Mickiewicz University in Poznań, Faculty of Chemistry, Umultowska 89b, 61-614 Poznań, Poland.

出版信息

Beilstein J Org Chem. 2019 Feb 4;15:310-332. doi: 10.3762/bjoc.15.28. eCollection 2019.

DOI:10.3762/bjoc.15.28
PMID:30800181
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6369983/
Abstract

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.

摘要

本综述总结了烯烃复分解反应在多面体低聚倍半硅氧烷（POSS）及含POSS聚合物材料的合成与功能化中的应用。讨论了三种反应过程，即乙烯基取代的POSS与末端烯烃的交叉复分解反应（CM）、二乙烯基取代的POSS与α,ω-二烯烃的开环易位聚合（ADMET）共聚反应，以及POSS取代的降冰片烯（或其他易发生开环易位聚合反应的环烯烃）的开环易位聚合（ROMP）反应。重点在于合成和催化方面，而非合成材料的性能和应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/57bb3f5f4c15/Beilstein_J_Org_Chem-15-310-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/763c07d5231e/Beilstein_J_Org_Chem-15-310-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/4086263d0cf3/Beilstein_J_Org_Chem-15-310-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/503d32f63d2e/Beilstein_J_Org_Chem-15-310-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/21c3d558d378/Beilstein_J_Org_Chem-15-310-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/66b51991ea83/Beilstein_J_Org_Chem-15-310-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/57bb3f5f4c15/Beilstein_J_Org_Chem-15-310-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/763c07d5231e/Beilstein_J_Org_Chem-15-310-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/4086263d0cf3/Beilstein_J_Org_Chem-15-310-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/503d32f63d2e/Beilstein_J_Org_Chem-15-310-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/21c3d558d378/Beilstein_J_Org_Chem-15-310-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/66b51991ea83/Beilstein_J_Org_Chem-15-310-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd81/6369983/57bb3f5f4c15/Beilstein_J_Org_Chem-15-310-g017.jpg

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