乙烯基功能化的Janus环硅氧烷：混合功能材料的潜在前体

Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials.

作者信息

Chaiprasert Thanawat, Liu Yujia, Takeda Nobuhiro, Unno Masafumi

机构信息

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu 376-8515, Japan.

出版信息

Materials (Basel). 2021 Apr 16;14(8):2014. doi: 10.3390/ma14082014.

DOI:10.3390/ma14082014

PMID:33923699

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8073502/

Abstract

A vinyl-functionalized all--tetrasiloxycyclotetrasiloxane [ViSi(OSiMeH)O] (Vi = vinyl group) Janus precursor was prepared from potassium cyclotetrasiloxane silanolate. The Janus precursor was selectively modified at its dimethylhydrosilyl groups [-SiMeH] via the Piers-Rubinsztajn reaction to obtain a family of new tetravinyl-substituted Janus rings [ViSi(OR')O] containing various functional groups in moderate yields. Remarkably, the tetravinyl groups on the structure remained intact after modification by the Piers-Rubinsztajn reaction. Since these synthesized compounds possess multiple functional groups (up to eight per molecule), they are potential precursors for advanced hybrid organic-inorganic functional materials.

摘要

一种乙烯基官能化的全四硅氧基环四硅氧烷[ViSi(OSiMeH)O]（Vi = 乙烯基）Janus前驱体由环四硅氧烷硅醇钾盐制备而成。通过皮尔斯-鲁宾斯泰因反应，该Janus前驱体在其二甲基氢硅烷基团[-SiMeH]上被选择性修饰，从而以中等产率获得了一系列含有各种官能团的新型四乙烯基取代Janus环[ViSi(OR')O]。值得注意的是，通过皮尔斯-鲁宾斯泰因反应修饰后，结构上的四乙烯基保持完整。由于这些合成化合物具有多个官能团（每个分子最多八个），它们是先进的有机-无机杂化功能材料的潜在前驱体。