由 NNNN 型大环稳定的阳离子镁氢化物[MgH]。
Cationic magnesium hydride [MgH] stabilized by an NNNN-type macrocycle.
机构信息
Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany.
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA.
出版信息
Chem Commun (Camb). 2019 Mar 18;55(22):3199-3202. doi: 10.1039/c9cc00490d. Epub 2019 Feb 25.
PMID:30801600
Abstract
A magnesium hydride cation [(L)MgH] supported by a macrocyclic ligand (L = MeTACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgHMg{N(SiMe)}] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
摘要
一种由大环配体（L = MeTACD；1,4,7,10-四甲基-1,4,7,10-四氮杂环十二烷）稳定的氢化镁阳离子[(L)MgH]，通过混合酰胺氢化物[(L)MgHMg{N(SiMe)}]的部分质子化制备，并被证明能够与包括吡啶在内的不饱和底物发生多种反应。
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