J. Heyrovský Institute of Physical Chemistry of the Czech Academy of Sciences, Dolejškova 3, 18223 Prague, Czech Republic.
Chem Commun (Camb). 2019 Mar 14;55(23):3351-3354. doi: 10.1039/c8cc09681c.
Four molecules containing identical tripodal anchors and p-oligophenylene molecular wires of increasing length were used to demonstrate tuning of the asymmetric molecular junction to the desired geometry by probabilistic mapping of single molecule junction configurations in a scanning tunnelling microscopy break junction experiment.
四个分子,它们均含有相同的三脚形锚和逐渐增长的 p-聚亚苯基分子导线,通过在扫描隧道显微镜断键实验中,对单个分子结构型进行概率映射,来证明通过概率映射可以将不对称分子结调谐到所需的几何形状。