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核壳结构 CdS/聚多巴胺/TiO 三元杂化物作为高效可见光光催化剂。

Core/shell structured CdS/polydopamine/TiO ternary hybrids as highly active visible-light photocatalysis.

机构信息

Guangling College, Yangzhou University, Yangzhou, Jiangsu 225009, PR China; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, PR China.

Guangling College, Yangzhou University, Yangzhou, Jiangsu 225009, PR China.

出版信息

J Colloid Interface Sci. 2019 May 15;544:1-7. doi: 10.1016/j.jcis.2019.02.080. Epub 2019 Feb 23.

DOI:10.1016/j.jcis.2019.02.080
PMID:30818155
Abstract

Core/shell structured CdS/polydopamine/TiO (CdS/PDA/TiO) ternary hybrids were fabricated by sequentially coating of PDA and TiO on CdS nanospheres through dopamine self-polymerization and TBOT hydrolysis and hydrothermal processes. The reaction rate constants of CdS/PDA/TiO ternary hybrids toward the degradation of RhB, MB and phenol were more than 3 times higher than those of CdS/TiO hybrids. The remarkably improved photocatalytic activity was attributed to enhanced light absorption and charge carrier separation efficiency associated with the introduction of PDA.

摘要

核壳结构的 CdS/聚多巴胺/二氧化钛(CdS/PDA/TiO)三元杂化物是通过多巴胺自聚合和 TBOT 水解及水热过程,将 PDA 和 TiO 依次包覆在 CdS 纳米球上制备的。CdS/PDA/TiO 三元杂化物对 RhB、MB 和苯酚的降解反应速率常数比 CdS/TiO 杂化物高 3 倍以上。显著提高的光催化活性归因于引入 PDA 后增强的光吸收和载流子分离效率。

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