Mohr Markus, Wunderlich Rainer K, Zweiacker Kai, Prades-Rödel Silke, Sauget Romuald, Blatter Andreas, Logé Roland, Dommann Alex, Neels Antonia, Johnson William L, Fecht Hans-Jörg
1Institute of Functional Nanosystems FNS, Ulm University, Albert-Einstein-Allee 47, 89081 Ulm, Germany.
2Center for X-ray Analytics, Empa Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland.
NPJ Microgravity. 2019 Feb 25;5:4. doi: 10.1038/s41526-019-0065-4. eCollection 2019.
Here we present measurements of surface tension and viscosity of the bulk glass-forming alloy PdCuNiP performed during containerless processing under reduced gravity. We applied the oscillating drop method in an electromagnetic levitation facility on board of parabolic flights. The measured viscosity exhibits a pronounced temperature dependence following an Arrhenius law over a temperature range from 1100 K to 1450 K. Together with literature values of viscosity at lower temperatures, the viscosity of PdCuNiP can be well described by a free volume model. X-ray diffraction analysis on the material retrieved after the parabolic flights confirm the glassy nature after vitrification of the bulk samples and thus the absence of crystallization during processing over a wide temperature range.
在此,我们展示了在微重力环境下进行无容器处理期间对块状玻璃形成合金PdCuNiP的表面张力和粘度的测量结果。我们在抛物线飞行的电磁悬浮装置中应用了振荡滴法。在1100K至1450K的温度范围内,测得的粘度呈现出明显的温度依赖性,遵循阿仑尼乌斯定律。结合较低温度下的粘度文献值,PdCuNiP的粘度可以用自由体积模型很好地描述。对抛物线飞行后回收的材料进行的X射线衍射分析证实了块状样品玻璃化后的玻璃性质,因此在宽温度范围内加工过程中不存在结晶现象。