Straub Mark D, Leduc Jennifer, Frank Michael, Raauf Aida, Lohrey Trevor D, Minasian Stefan G, Mathur Sanjay, Arnold John
Department of Chemistry, University of California, Berkeley, Berkeley, CA, 94720, USA.
Heavy Element Chemistry Group, Chemical Sciences Division, Lawrence Berkeley National Lab, Berkeley, CA, 94720, USA.
Angew Chem Int Ed Engl. 2019 Apr 16;58(17):5749-5753. doi: 10.1002/anie.201901924. Epub 2019 Mar 20.
Homoleptic uranium(IV) amidate complexes have been synthesized and applied as single-source molecular precursors for the chemical vapor deposition of UO thin films. These precursors decompose by alkene elimination to give highly crystalline phase-pure UO films with an unusual branched heterostructure.
已合成了均配型铀（IV）酰胺配合物，并将其用作化学气相沉积UO薄膜的单源分子前驱体。这些前驱体通过烯烃消除反应分解，得到具有异常分支异质结构的高度结晶的纯相UO薄膜。
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