Chen Guangbo, Waterhouse Geoffrey I N, Shi Run, Zhao Jiaqing, Li Zhenhua, Wu Li-Zhu, Tung Chen-Ho, Zhang Tierui
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
Center for Advancing Electronics Dresden and Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062, Dresden, Germany.
Angew Chem Int Ed Engl. 2019 Dec 2;58(49):17528-17551. doi: 10.1002/anie.201814313. Epub 2019 Sep 13.
Catalytic C chemistry based on the activation/conversion of synthesis gas (CO+H ), methane, carbon dioxide, and methanol offers great potential for the sustainable development of hydrocarbon fuels to replace oil, coal, and natural gas. Traditional thermal catalytic processes used for C transformations require high temperatures and pressures, thereby carrying a significant carbon footprint. In comparison, solar-driven C catalysis offers a greener and more sustainable pathway for manufacturing fuels and other commodity chemicals, although conversion efficiencies are currently too low to justify industry investment. In this Review, we highlight recent advances and milestones in light-driven C chemistry, including solar Fischer-Tropsch synthesis, the water-gas-shift reaction, CO hydrogenation, as well as methane and methanol conversion reactions. Particular emphasis is placed on the rational design of catalysts, structure-reactivity relationships, as well as reaction mechanisms. Strategies for scaling up solar-driven C processes are also discussed.
基于合成气（CO+H₂）、甲烷、二氧化碳和甲醇的活化/转化的催化碳化学，为可持续发展烃类燃料以替代石油、煤炭和天然气提供了巨大潜力。用于碳转化的传统热催化过程需要高温高压，因此具有显著的碳足迹。相比之下，太阳能驱动的碳催化为制造燃料和其他商品化学品提供了更绿色、更可持续的途径，尽管目前的转化效率过低，无法证明行业投资的合理性。在本综述中，我们重点介绍了光驱动碳化学的最新进展和里程碑，包括太阳能费托合成、水煤气变换反应、CO加氢以及甲烷和甲醇转化反应。特别强调了催化剂的合理设计、结构-反应性关系以及反应机理。还讨论了扩大太阳能驱动碳过程规模的策略。
